Role of magnetic nanoparticles incorporation for the enhanced efficiency of ZnO based Dye-Sensitized Solar Cells (DSSCs)


  • Noor Abdallah university of Basrah,College of Science, Department of physics.
  • Basil A Abdullah University of Basrah ,College of Science ,Department of Physics. Iraq
  • Hashim Jabbar University of Basrah ,College of Science ,Department of Physics. Iraq



: Dye sensitized solar cells, Zno nanoparticles, magnetic Field effect, MnCoFeo4, Ferrimagnetism


In this study, we reported on the effect of the internal magnetic field arising from magnetic particles added to zinc oxide in certain proportions, which led to an improvement in the performance of the dye solar cell, We found that the magnetic effect It is the main factor that improves the ability to transfer electrons generated from the separation process between (electron-hole) pairs, And reduce the process of reunification between electrons and holes, The efficiency of the cell with a pure electrode was (1.38%), while the highest efficiency we got after doping was when doping with a ratio (97%ZnO+3%MnCoFeO4) reached (1.7%), i.e. the percentage increase in efficiency (23%).


M. Grätzel, “Solar energy conversion by dye-sensitized photovoltaic cells,” Inorg. Chem., vol. 44, no. 20, pp. 6841–6851, 2005, doi: 10.1021/ic0508371.

Y. K. Sanusi, A. A. Kazeem, and K. O. Suleman, “Photoanode Thickness and Sensitization Time Effects on Overall Performance of Nanocrystalline TiO2 Based Solar Cell Sensitized with Roselle Flower Extracts,” Int. J. Sci., vol. 7, no. 5, pp. 345–350, 2016.

W. Shockley and H. J. Queisser, “Detailed balance limit of efficiency of p-n junction solar cells,” J. Appl. Phys., vol. 32, no. 3, pp. 510–519, 1961, doi: 10.1063/1.1736034.

Rahmayeni, A. Devi, Y. Stiadi, N. Jamarun, Emriadi, and S. Arief, “Preparation, characterization of ZnO/CoFe2O4 magnetic nanocomposites and activity evaluation under solar light irradiation,” J. Chem. Pharm. Res., vol. 7, no. 9, pp. 139–146, 2015.

H. Jabbar, B. A. Abdullah, and N. Ahmad, “Tuning TiO 2 Porosity of Multilayered Photoanode Towards Enhanced Performance of Dye Sensitized Solar Cell,” Al-Mustansiriyah J. Sci., vol. 33, no. 4, pp. 0–4, 2022.

J. Barber and B. Andersson, “Revealing the blueprint of photosynthesis,” Nature, vol. 370, no. 6484. pp. 31–34, 1994. doi: 10.1038/370031a0.

N. Rajamanickam, S. S. Kanmani, K. Jayakumar, and K. Ramachandran, “On the possibility of ferromagnetism and improved dye-sensitized solar cells efficiency in TiO 2 /ZnO core/shell nanostructures,” J. Photochem. Photobiol. A Chem., vol. 378, no. March, pp. 192–200, 2019, doi: 10.1016/j.jphotochem.2019.04.042.

Y. M. Xiao et al., “Low temperature fabrication of high performance and transparent Pt counter electrodes for use in flexible dye-sensitized solar cells,” Chinese Sci. Bull., vol. 57, no. 18, pp. 2329–2334, 2012, doi: 10.1007/s11434-012-5110-6.

R. Elshypany et al., “Elaboration of Fe3O4/ZnO nanocomposite with highly performance photocatalytic activity for degradation methylene blue under visible light irradiation,” Environ. Technol. Innov., vol. 23, 2021, doi: 10.1016/j.eti.2021.101710.

S. Agarwal, L. K. Jangir, K. S. Rathore, M. Kumar, and K. Awasthi, “Morphology-dependent structural and optical properties of ZnO nanostructures,” Appl. Phys. A Mater. Sci. Process., vol. 125, no. 8, 2019, doi: 10.1007/s00339-019-2852-x.

K. C. B. Naidu and W. Madhuri, “Hydrothermal synthesis of NiFe2O4 nano-particles: Structural, morphological, optical, electrical and magnetic properties,” Bull. Mater. Sci., vol. 40, no. 2, pp. 417–425, 2017, doi: 10.1007/s12034-017-1374-4.

A. Baouid, S. Elhazazi, A. Hasnaoui, P. Compain, J. P. Lavergne, and F. Huet, “Highly peri-, regio- and diastereoselective 1,3-dipolar cycloaddition of mesitonitrile oxide to 1,7-dimethyl-2,3-dihydro-1H-1,4-diazepines: Unexpected one-step formation of a new triheterocyclic framework,” New J. Chem., vol. 25, no. 12, pp. 1479–1481, 2001, doi: 10.1002/chin.200229170.

S. Munir et al., “Nickel ferrite/zinc oxide nanocomposite: Investigating the photocatalytic and antibacterial properties,” J. Saudi Chem. Soc., vol. 25, no. 12, p. 101388, 2021, doi: 10.1016/j.jscs.2021.101388.

X. Xu, C. Xu, Y. Lin, J. Li, and J. Hu, “Comparison on photoluminescence and magnetism between two kinds of undoped ZnO nanorods,” J. Phys. Chem. C, vol. 117, no. 46, pp. 24549–24553, 2013, doi: 10.1021/jp405662y.

U. Routray, R. Dash, J. R. Mohapatra, J. Das, V. V. Srinivasu, and D. K. Mishra, “Temperature-dependent ferromagnetic behavior in nanocrystalline ZnO synthesized by pyrophoric technique,” Mater. Lett., vol. 137, pp. 29–31, 2014, doi: 10.1016/j.matlet.2014.08.109.

S. Pattanaik, B. Biswal, U. Routray, J. Mohapatra, V. V. Srinivasu, and D. K. Mishra, “Oxygen vacancy induced ferromagnetism in ball milled Zn0.97Ni0.03O: Confirmation through electron spin resonance,” Mater. Today Proc., vol. 35, no. xxxx, pp. 141–144, 2021, doi: 10.1016/j.matpr.2020.03.547.

D. A. Shalybkov and V. A. Urpin, “The hall effect and oscillating decay of a magnetic field,” Tech. Phys., vol. 45, no. 2, pp. 147–152, 2000, doi: 10.1134/1.1259587.

F. Cai, S. Zhang, and Z. Yuan, “Effect of magnetic gamma-iron oxide nanoparticles on the efficiency of dye-sensitized solar cells,” RSC Adv., vol. 5, no. 53, pp. 42869–42874, 2015, doi: 10.1039/c5ra05936d.

B. Govindarajan, R. Palanimuthu, and K. M. Manikandan, “Influence of Mg doping in magnetic properties of NiO nanoparticles and its electrical applications,” J. Mater. Sci. Mater. Electron., vol. 30, no. 7, pp. 6519–6527, 2019, doi: 10.1007/s10854-019-00957-2.

H. S. E. Kouhestanian, M. Ranjbar, S. A. Mozaffari, “Investigating the Effects of Thickness on the Performance of ZnO-Based DSSC,” Iran. Res. Organ. Sci. Technol., vol. 14, pp. 101–112, 2021.

H. S. Kang, W. S. Kim, Y. K. Kshetri, H. S. Kim, and H. H. Kim, “Enhancement of Efficiency of a TiO2-BiFeO3 Dye-Synthesized Solar Cell through Magnetization,” Materials (Basel)., vol. 15, no. 18, 2022, doi: 10.3390/ma15186367.

Q. Zhang, C. S. Dandeneau, X. Zhou, and C. Cao, “ZnO nanostructures for dye-sensitized solar cells,” Adv. Mater., vol. 21, no. 41, pp. 4087–4108, 2009, doi: 10.1002/adma.200803827.

E. Frankevich and A. Zakhidov, “Photoconductivity of poly „ 2 , 5-diheptyloxy- p -phenylene vinylene … in the air atmosphere : Magnetic-field effect and mechanism of generation and recombination of charge carriers,” Inst. Mol. Sci. Myodaiji, Okazaki, 444, Japan, vol. 53, no. 8, pp. 4498–4508, 1996.








How to Cite

Role of magnetic nanoparticles incorporation for the enhanced efficiency of ZnO based Dye-Sensitized Solar Cells (DSSCs). (2023). University of Thi-Qar Journal of Science, 10(2), 115-121.