Assessment of heavy metals contamination of agricultural soils using pollution indicators in Thi-Qar governorate, Southern Iraq
DOI:
https://doi.org/10.32792/utq/utjsci/v10i2.1064Abstract
This study aims to assess the levels of contamination of agricultural soils with heavy elements (cobalt, copper, iron, nickel, cadmium, and lead) in three regions in Thi-Qar Governorate, Southern Iraq. These three regions are Al-Gharraf, Al-Islah, and Al-Batha. The study was done by using the pollution indicators, which are geographical pollution index (Igeo), contamination degree (Cd), contamination factor (Cf), pollution load index (PLI), potential ecological risk factor (Er), and finally, risk index (RI). From each region, four soil samples were collected from holes 25 cm deep, separated by a distance of 500 meters. After the digestion process of the samples, the concentrations of the studied elements were measured by flam atomic absorption spectrometer (FAAS). The results showed that the average heavy metal concentrations for all samples were (365.810, 96.424, 41.36, 11.919, 5.194 and 0.352 mg/kg). They were in the following order Fe > Ni > Cu >Co > Pb > Cd, respectively. The concentrations of heavy metals in the study areas were all within the limits allowed by the World Health Organization (WHO) except for 8.3% of the studied areas that were beyond the permissible limits for cadmium only. The reason for the increase in cadmium concentrations in some areas could be due to sewage, industrial emissions and agricultural practices. According to the Igeo values, the levels of minerals studied for the three regions followed the following order Cd > Cu > Co > Pb > N i> Fe.
Received: 2023-06-28
Revised: 2023-08-20
Accepted: 2023-08-28
References
B. Y. Mohammed , J. A. Umar, and S. I. Mohammed, “Assessment of soil degradation under agricultural land use sites: Emerging evidence from the Savanna Region of North Eastern Nigeria", Ghana Journal of Geography, vol. 11, no. 2, pp. 243-263, 2019.
I. A. K, B. M, and M. Z, “Soil degradation assessment of some selected land use in two Agro ecological zones of Gombe State, Nigeria”, Journal of Agricultural Science and Practice, vol. 7, no. 4, pp. 52–60, 2022.
W. A. Iyama, , K. Okpara, and K. Techato, “Assessment of heavy metals in agricultural soils and plant (Vernonia amygdalina delile) in port harcourt metropolis, Nigeria”, Agriculture, vol. 12, no. 1, pp. 27, 2021.
M. Koller, and H. M. Saleh, “Introductory chapter: Introducing heavy metals”, Heavy metals, vol. 1, pp. 3-11, 2018.
[5] S. Salman, E. Abou El-Anwar, A. Asmoay, H. Mekky, W. Abdel Wahab, and A. Elnazer, “Chemical Fractionation and Risk Assessment of Some Heavy Metals in Soils, Assiut Governorate, Egypt”, Egyptian Journal of Chemistry, vol. 64, no. 7, pp. 3311–3321, 2021.
S. M. Othman, S. I. Sarsam, and S. A. Ismail, “Gypsum and limestone dissolution within Fatha Formation (Middle Miocene) at various pH solutions: A laboratory study”, The Iraqi Geological Journal, pp. 71–88, 2020.
A. H. Al-Obeidi, and H. A. Al-Jumaily, “Geochemistry and environmental assessment of heavy metals in surface soil in Al-Hawija, southwest Kirkuk”, The Iraqi Geological Journal, pp. 36-61, 2020.
G. Qin, Z. Niu, J. Yu, Z. Li, J. Ma, and P. Xiang, “Soil heavy metal pollution and food safety in China: Effects, sources and removing technology”, Chemosphere, vol. 267, p. 129205, Mar. 2021.
K. Khan, Y. Lu, H. Khan, M. Ishtiaq, S. Khan, M. Waqas, et al., “Heavy metals in agricultural soils and crops and their health risks in Swat District, northern Pakistan”, Food and chemical toxicology, vol. 58, pp. 449-458, 2013.
S. Ethaib, “Solid Waste Situation in Thi-Qar Governorate”, IOP Conference Series: Materials Science and Engineering, vol. 584, p. 012023, 2019.
Japu, Thi Qar governorate profile, 26/03/2015.http://www.jauiraq.org/gp/print/GP-thi-qar.asp.
M. Taghavi, Mostafa Darvishiyan, M. Momeni, H. Eslami, Reza Ali Fallahzadeh, and A. Zarei, “Ecological risk assessment of trace elements pollution and human health risk exposure in agricultural soils used for Saffron cultivation”, Research Square (Research Square), 2022.
F. Ahmed, and H. Ishiga, “Trace metal concentrations in street dusts of Dhaka city, Bangladesh”, Atmospheric Environment, vol. 40, no. 21, pp. 3835-3844, 2006.
M. I. Ahamad, J. Song, H. Sun, X. Wang, M. S. Mehmood, M. Sajid, et al., “Contamination level, ecological risk, and source identification of heavy metals in the hyporheic zone of the Weihe River, China”, International journal of environmental research and public health, vol. 17, no. 3, pp. 1070, 2020.
M. Bineshpour, K. Payandeh, A. Nazarpour, and S. Sabzalipour, “Assessment of Human Health Risk and Surface Soil Contamination by Some Toxic Elements in Arak City, Iran,” Journal of Advances in Environmental Health Research, vol. 9, no. 4, pp. 321–332, 2021.
A. Alahabadi, and H. Malvandi, “Contamination and ecological risk assessment of heavy metals and metalloids in surface sediments of the Tajan River, Iran”, Marine Pollution Bulletin, vol. 133, pp. 741-749, 2018.
[17] L. Hakanson, “An ecological risk index for aquatic pollution control. A sedimentological approach", Water research, vol. 14, no. 8, pp. 975-1001, 1980.
D. L. Tomlinson, J. G. Wilson, C. R. Harris, and D. W. Jeffrey, “Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index”, Helgoländer Meeresuntersuchungen, vol. 33, no. 1–4, pp. 566–575, 1980.
I. A. Al-Ali, “Assessing sediment pollution by applying some geochemical indices for Al-Wind River banks/East of Iraq", Iraqi Journal of Science, pp. 1711-1719, 2019.
G. Müller, “Die Schwermetallbelastung der sedimente des Neckars und seiner Nebenflusse: eine Bestandsaufnahme”, Chem. Ztg., vol. 105, pp. 157–164, 1981.
C. E. F. Monjardin, D. B. Senoro, J. J. M. Magbanlac, K. L. M. de Jesus, C. B. Tabelin, and P. M. Natal, “Geo-Accumulation Index of Manganese in Soils Due to Flooding in Boac and Mogpog Rivers, Marinduque, Philippines with Mining Disaster Exposure”, Applied Sciences, vol. 12, no. 7, p. 3527, 2022.
M. Kuerban, B. Maihemuti, Y. Waili, and T. Tuerhong, “Ecological risk assessment and source identification of heavy metal pollution in vegetable bases of Urumqi, China, using the positive matrix factorization (PMF) method”, PloS one, vol. 15, no. 4, pp. e0230191, 2020.
K. C. Ajah, J. Ademiluyi, and C. C. Nnaji, “Spatiality, seasonality and ecological risks of heavy metals in the vicinity of a degenerate municipal central dumpsite in Enugu, Nigeria”, Journal of Environmental Health Science and Engineering, vol. 13, pp. 1-15, 2015.
T. M. Chiroma, R. O. Ebewele, and F. K. Hymore, “Comparative assessment of heavy metal levels in soil, vegetables and urban grey waste water used for irrigation in Yola and Kano”, International refereed journal of engineering and science, vol. 3, no. 2, pp. 01-09, 2014.
[25] M. Alsafran, M. H. Saleem, H. Al Jabri, M. Rizwan, and K. Usman, “Principles and applicability of integrated remediation strategies for heavy metal Removal/Recovery from contaminated environments”, Journal of Plant Growth Regulation, vol. 42, no. 6, pp. 3419-3440, 2023. .
A. Al-Bedhany, “Geochemical evaluation pollution for some heavy metals in basra soil”, University of Thi-Qar Journal of Science, vol. 5, no. 2, pp. 34-42, 2015.
M. M. El-Sherbiny, A. I. Ismail, and M. E. El-Hefnawy, “A preliminary assessment of potential ecological risk and soil contamination by heavy metals around a cement factory, western Saudi Arabia”, Open Chemistry, vol. 17, no. 1, pp. 671-684, 2019.
A. K. H. Al-Rubaiee, and M. R. Al-Owaidi, “Assessment of heavy metal contamination in urban soils of selected areas in Hilla City, Babylon, Iraq”, Iraqi Journal of Science, pp. 1627-1641, 2022.
S. Norbaya, M. Ripin, S. Hasan, M. Lias Kamal, and N. Hashim, “Analysis And Pollution Assessment Of Heavy Metal In Soil, Perlis (Analisis dan Penilaian Pencemaran Logam Berat dalam Tanah, Perlis)”, The Malaysian Journal of Analytical Sciences, vol. 18, no. 1, pp. 155–161, 2014.
I. A. Kahdim, and S. T. Jawad, “Assessment the concentration of some heavy metals of selected soils from Shattrah city”, Journal Of Thi-Qar Science, vol. 6, no. 1, pp. 45-51, 2016.
Y. Zhao, Q. Deng, Q. Lin, C. Zeng, and C. Zhong, “Cadmium source identification in soils and high-risk regions predicted by geographical detector method”, Environmental Pollution, vol. 263, p. 114338, 2020.
Downloads
Published
License
Copyright (c) 2023 University of Thi-Qar Journal of Science
This work is licensed under a Creative Commons Attribution 4.0 International License.